Poster Presentation Society for Freshwater Science 2025 Annual Meeting

Emissions of volatile organic compounds (VOCs) from shallow eutrophic UK reservoirs that supply drinking water (118876)

Faith L Imhanze 1 , Helen C Glanville 1 , Dave B Ryves 1 , Jim C Reynolds 2
  1. Geography and Environment, Loughborough University, Loughborough, Leicestershire, United Kingdom
  2. Chemistry, Loughborough University, Loughborough, Leicestershire, United Kingdom

Freshwater eutrophication, driven by excess nitrogen and phosphorus, leads to algal blooms and degraded water quality, exacerbated by anthropogenic activities such as wastewater mismanagement and agricultural runoff (Yang et al. 2022). Constructing dams (impoundment) to create reservoirs significantly alters the hydrological dynamics of rivers, influencing water retention, quality, and volatile organic compound (VOC) emissions (Krajenbrink et al. 2019). Management operations like drawdowns and climate change-induced droughts expose sediments to atmospheric conditions, enhancing the release of odorous VOCs, including geosmin, 2-MIB, and β-cyclocitral. These compounds cause taste and odour issues in drinking water (Pozzer et al. 2022), yet little research has examined their sources and dynamics in UK reservoirs.

This study investigates the impact of impoundment, seasonal changes, and climate-driven drought on VOC emissions from eutrophic drinking water reservoirs in the Midlands, UK. The research focuses on two reservoirs managed by Severn Trent Water: Swithland, which experienced severe drought (2018–2022; down to 20 – 25% of capacity) and recent refilling to full capacity (2024), and Lower Shustoke, which struggles with algal blooms. Seasonal water and sediment samples will be analysed using modified Solid Phase Micro-Extraction (SPME) and Gas Chromatography (Lu et al. 2012). Historical water level and abstraction data will also be examined to correlate VOC emissions with anthropogenic and climatic stressors.

Preliminary findings suggest that Swithland will exhibit a more diverse VOC profile, with elevated levels of geosmin, 2-MIB, and β-cyclocitral, particularly in summer. This study will elucidate the link between sediment exposure, resuspension, and VOC emissions, providing critical insights into water quality degradation. The findings will contribute to sustainable reservoir management strategies, guiding mitigation efforts to ensure safe, palatable drinking water supplies.

  1. Krajenbrink, H. J., M. Acreman, M. J. Dunbar, L. Greenway, D. M. Hannah, C. L. R. Laizé, D. B. Ryves, and P. J. Wood. 2019. Diatoms as indicators of the effects of river impoundment at multiple spatial scales 7:e8092.
  2. Lu, X., C. Fan, J. Shang, J. Deng, and H. Yin. 2012. Headspace solid-phase microextraction for the determination of volatile sulfur compounds in odorous hyper-eutrophic freshwater lakes using gas chromatography with flame photometric detection. Microchemical Journal 104:26–32.
  3. Pozzer, A. C., P. A. Gómez, and J. Weiss. 2022. Volatile organic compounds in aquatic ecosystems – Detection, origin, significance and applications. Science of The Total Environment 838:156155.
  4. Yang, X., X. Deng, G. Li, Y. Liu, and Q. Gao. 2022. Human activities aggravate VOC pollution in the Huangshui River of the Tibetan Plateau. Sustainability 14(9):11983